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Elasticity and high-pressure structure of arsenoflorencite-(La): insights into the high-pressure behaviour of the alunite supergroup

Published online by Cambridge University Press:  05 July 2018

S. J. Mills  and
F. Nestola
S. J. Mills*
Affiliation:
Geosciences, Museum Victoria, GPO Box 666, Melbourne 3001, Victoria, Australia
F. Nestola
Affiliation:
Department of Geosciences, University of Padua, Via Gradenigo 6, I-35131 Padova, Italy
*
*E-mail: [email protected]
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Abstract

Arsenoflorencite-(La), ideally LaAl3(AsO4)2(OH)6, was studied at high pressure by single-crystal X-ray diffractometry. The unit cell was determined at nine pressures up to 7.471(8) GPa; no evidence of a phase transformation was found in this range. The pressure volume data (refined simultaneously) were fitted to a third-order Birch Murnaghan equation of state which gave V0 = 710.71(8) Å3, KT0 = 106(2) GPa and K' = 9.2(9). These values were confirmed independently from an FE–fE plot. The crystal structure was refined at 1.596, 3.622, 5.749 and 7.471 GPa, the first time this has been done for a member the alunite supergroup. The compressibility of arsenoflorencite-(La) is strongly anisotropic, with βc > βa. The main compression mechanism was found to be governed by the internal angle O3 La O2 of the La polyhedron, where the O2 and O3 atoms move toward the c axis during compression.

Keywords

high pressurecrystal structurealunite supergrouparsenoflorencite-(La)jarosite
Type
Research Article
Information
Mineralogical Magazine , Volume 76 , Issue 4 , August 2012 , pp. 975 - 985
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2012

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