Hostname: page-component-586b7cd67f-tf8b9 Total loading time: 0 Render date: 2024-11-24T14:01:47.733Z Has data issue: false hasContentIssue false
  • English
  • Français

Surface Reconstruction and Oxide Nucleation Due to Oxygen Interaction with Cu(001) Observed by In Situ Ultra-High Vacuum Transmission Electron Microscopy

Published online by Cambridge University Press:  28 July 2005

Judith C. Yang ,
Mark Yeadon ,
Borys Kolasa  and
J. Murray Gibson
Judith C. Yang
Affiliation:
Frederick Seitz Materials Research Laboratory, 104 South Goodwin Avenue, University of Illinois at Urbana-Champaign, Urbana, IL 61801
Mark Yeadon
Affiliation:
Institute of Materials Research and Engineering, National University of Singapore, Singapore 119260, Republic of Singapore
Borys Kolasa
Affiliation:
Frederick Seitz Materials Research Laboratory, 104 South Goodwin Avenue, University of Illinois at Urbana-Champaign, Urbana, IL 61801
J. Murray Gibson
Affiliation:
Frederick Seitz Materials Research Laboratory, 104 South Goodwin Avenue, University of Illinois at Urbana-Champaign, Urbana, IL 61801
Get access

Abstract

Reconstruction of the Cu(001) surface due to oxygen gas impingement on a clean copper surface was directly observed by in situ UHV-TEM. Strain contrast between differently oriented surface reconstruction domains, assumed to be √2 × 2√2 R45, were clearly visible by this method. The reconstruction precedes the nucleation of Cu2O islands. When Cu2O islands were partially reduced and then re-oxidized, a dwell time before formation of Cu2O was noted, demonstrating that a reconstructed Cu-O surface monolayer is necessary before oxide formation.

Keywords

in situtransmission electron microscopyCuCu2Othin filmsoxidationsurface reconstruction
Type
1998 ASU ELECTRON MICROSCOPY WORKSHOP
Information
Microscopy and Microanalysis , Volume 4 , Issue 3 , June 1998 , pp. 334 - 339
Copyright
© 2005 Microscopy Society of America

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)