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Direct Contacting with Liquid Electrolyte Facilitates the Surface Phase Transition in Ni-rich Layered Cathode

Published online by Cambridge University Press:  30 July 2020

Lianfeng Zou ,
Wengao Zhao ,
Haiping Jia ,
Jianming Zheng ,
Linze Li ,
Daniel Abraham ,
Guoying Chen ,
Jason Croy ,
Ji-Guang Zhang  and
Chongmin Wang
Lianfeng Zou
Affiliation:
Pacific Northwest National Laboratory, Richland, Washington, United States
Wengao Zhao
Affiliation:
Pacific Northwest National Laboratory, Richland, Washington, United States
Haiping Jia
Affiliation:
Pacific Northwest National Laboratory, Richland, Washington, United States
Jianming Zheng
Affiliation:
Pacific Northwest National Laboratory, Richland, Washington, United States
Linze Li
Affiliation:
Pacific Northwest National Laboratory, Richland, Washington, United States
Daniel Abraham
Affiliation:
ANL, Lemont, Illinois, United States
Guoying Chen
Affiliation:
LBNL, Berkeley, California, United States
Jason Croy
Affiliation:
ANL, Lemont, Illinois, United States
Ji-Guang Zhang
Affiliation:
Pacific Northwest National Laboratory, Richland, Washington, United States
Chongmin Wang
Affiliation:
Pacific Northwest National Laboratory, Richland, Washington, United States

Abstract

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Type
Energy and Soft Materials and the Development of Cryogenic Techniques for Studying Them
Information
Microscopy and Microanalysis , Volume 26 , Supplement S2 , August 2020 , pp. 3018 - 3020
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Copyright
Copyright © Microscopy Society of America 2020

References

Betz, J.; Brinkmann, J. P.; Nölle, R.; Lürenbaum, C.; Kolek, M.; Stan, M. C.; Winter, M.; Placke, T. Cross Talk between Transition Metal Cathode and Li Metal Anode: Unraveling Its Influence on the Deposition/Dissolution Behavior and Morphology of Lithium. Adv. Energy Mater. 2019, 9, 1900574.10.1002/aenm.201900574CrossRefGoogle Scholar
Gilbert, J. A.; Shkrob, I. A.; Abraham, D. P. Transition metal dissolution, ion migration, electrocatalytic reduction and capacity loss in lithium-ion full cells. J. Electrochem. Soc. 2017 , 164, A389-A399.10.1149/2.1111702jesCrossRefGoogle Scholar
Li, W.; Kim, U.-H.; Dolocan, A.; Sun, Y.-K.; Manthiram, A. Formation and inhibition of metallic lithium microstructures in lithium batteries driven by chemical crossover. ACS nano 2017 , 11, 5853-5863.10.1021/acsnano.7b01494CrossRefGoogle ScholarPubMed
Zheng, H.; Sun, Q.; Liu, G.; Song, X.; Battaglia, V. S. Correlation between dissolution behavior and electrochemical cycling performance for LiNi1/3Co1/3Mn1/3O2-based cells. J. Power Sources 2012 , 207, 134-140.10.1016/j.jpowsour.2012.01.122CrossRefGoogle Scholar
Zou, L.; Li, J.; Liu, Z.; Wang, G.; Manthiram, A.; Wang, C. Lattice doping regulated interfacial reactions in cathode for enhanced cycling stability. Nat. Commun. 2019 , 10, 3447.10.1038/s41467-019-11299-2CrossRefGoogle ScholarPubMed
Lin, F.; Markus, I. M.; Nordlund, D.; Weng, T.-C.; Asta, M. D.; Xin, H. L.; Doeff, M. M. Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries. Nat. Commun. 2014 , 5, 3529.10.1038/ncomms4529CrossRefGoogle ScholarPubMed
Maleki Kheimeh Sari, H.; Li, X. Controllable Cathode–Electrolyte Interface of Li [Ni0. 8Co0. 1Mn0. 1] O2 for Lithium Ion Batteries: A Review. Adv. Energy Mater. 2019 , 9, 1901597.10.1002/aenm.201901597CrossRefGoogle Scholar
Li, T.; Yuan, X.-Z.; Zhang, L.; Song, D.; Shi, K.; Bock, C. Degradation mechanisms and mitigation strategies of nickel-rich NMC-based lithium-ion batteries. Electrochem. Energy Rev. 2019, 1-38.Google Scholar
Lin, F.; Nordlund, D.; Li, Y.; Quan, M. K.; Cheng, L.; Weng, T.-C.; Liu, Y.; Xin, H. L.; Doeff, M. M. Metal segregation in hierarchically structured cathode materials for high-energy lithium batteries. Nat. Energy 2016 , 1, 15004.10.1038/nenergy.2015.4CrossRefGoogle Scholar