Hostname: page-component-cd9895bd7-mkpzs Total loading time: 0 Render date: 2024-12-18T22:51:52.207Z Has data issue: false hasContentIssue false
  • English
  • Français

Development and Application of a Sample Holder for In Situ Gaseous TEM Studies of Membrane Electrode Assemblies for Polymer Electrolyte Fuel Cells

Published online by Cambridge University Press:  30 August 2017

Takeo Kamino ,
Toshie Yaguchi  and
Takahiro Shimizu
Takeo Kamino*
Affiliation:
Fuel Cell Nanomaterials Center, University of Yamanashi, 6-43 Miyamae-cho, Kofu 400-0021, Japan Vacuum Device Inc.,1285-5 Iijima-cho, Mito, Ibaraki 311-4155, Japan
Toshie Yaguchi
Affiliation:
Advanced Microscope Systems Design Department, Hitachi High Technologies Corp., 882 Ichige, Hitachinaka, Ibaraki 312-0057, Japan
Takahiro Shimizu
Affiliation:
FC-EV Research Division, Japan Automobile Research Institute, 2530 Karima, Tsukuba, Ibaraki 305-0822, Japan
*
*Corresponding author. [email protected]
Get access

Abstract

Polymer electrolyte fuel cells hold great potential for stationary and mobile applications due to high power density and low operating temperature. However, the structural changes during electrochemical reactions are not well understood. In this article, we detail the development of the sample holder equipped with gas injectors and electric conductors and its application to a membrane electrode assembly of a polymer electrolyte fuel cell. Hydrogen and oxygen gases were simultaneously sprayed on the surfaces of the anode and cathode catalysts of the membrane electrode assembly sample, respectively, and observation of the structural changes in the catalysts were simultaneously carried out along with measurement of the generated voltages.

Keywords

in situ TEMpolymer electrolyte fuel cellmembrane electrode assemblyelectrochemical measurement
Type
Instrumentation and Software
Information
Microscopy and Microanalysis , Volume 23 , Issue 5 , October 2017 , pp. 945 - 950
Copyright
© Microscopy Society of America 2017 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Banares, M.A. (2005). Operando methodology: Combination of in situ spectroscopy and simultaneous activity measurements under catalytic reaction conditions. Catalysis Today 100, 71–77.CrossRefGoogle Scholar
Beale, A.M. & Sanker, G. (2006). In situ characterization of iron phosphate and bismuth molybdate catalysts prepared by hydrothermal methods: An EDXRD and combined XRD/XAS study. Nucl Instr Method Phys Res Sect B 199, 504–508.CrossRefGoogle Scholar
Boyes, E.D., Gai, P.L. & Hanna, L.G. (1997). Controlled environment TEM for dynamic in situ reaction studies with HREM lattice imaging. Mater Res Soc Symp Proc 404, 53–61.CrossRefGoogle Scholar
Fischer, C., Beweries, T., Preetz, A., Drexler, H.J., Baumann, W., Peitz, S., Rosenthal, U. & Heller, D. (2006). Kinetic and mechanistic investigation in homogeneous catalyst using UV/vis spectroscopy. Catalysis Today 155, 282–288.CrossRefGoogle Scholar
Gai, P.L. (1983). Microstructural changes in vanadium pentoxide in controlled environments. Philos Mag 48, 359–371.CrossRefGoogle Scholar
Hartl, K., Hanzlik, M. & Arenz, M. (2011). IL-TEM investigations on the degradation mechanism of Pt/C electrocatalysts with different carbon supports. Energy Environ Sci 4, 234–238.CrossRefGoogle Scholar
Janssen, A., Prestat, E., Haigh, S.J. & Burke, M.G. (2015). In situ analytical TEM of ilmenite reduction in hydrogen. Microsc Microanal 21(Suppl 3), 565–566.CrossRefGoogle Scholar
Kamino, T., Yaguchi, T., Konno, M., Watabe, A., Marukawa, T., Mima, T., Kuroda, K., Saka, H., Arai, S., Makino, H., Suzuki, Y. & Kishita, K. (2005). Development of a gas injection/specimen heating holder for use with transmission electron microscope. J Electron Microsc 54, 497–503.CrossRefGoogle ScholarPubMed
Kamino, T., Yaguchi, T., Konno, M., Watabe, A. & Nagakubo, Y. (2006). Development of a specimen heating holder with an evaporator and a gas injector and its application for catalyst. J Electron Microsc 55(5), 245–252.Google Scholar
Kimata, M., Tokuda, T., Tsuchinaga, A., Matsushima, T., Abe, H. & Tokashiki, N. (2010). Vacuum packaging technology for uncooled infrared sensor. IEEE J Trans 5, 175–180.Google Scholar
Kishita, K., Saka, H., Tanaka, H., Kuroda, K., Sakamoto, M., Watabe, A. & Kamino, T. (2009). Development of an analytical environmental TEM system and its application. J Electron Microsc 58, 331–339.CrossRefGoogle ScholarPubMed
Kulzick, M.A., Prestat, E., Dietrich, P.J., Doskocil, E., Haigh, S.J., Burke, M.G., Zaluzec, N.J. & Arenz, M. (2016). Temperature programmed reduction of a PdCu bimetallic catalyst via atmospheric pressures in situ STEM-EDS and in situ X-ray adsorption analysis. Microsc Microanal 22(Suppl 3), 214–215.CrossRefGoogle Scholar
Mayrhofer, K.J., Ashton, S.J., Meier, J.C., Wiberg, K.H., Hanzlik, M. & Arenz, M. (2008). Non-destructive transmission electron microscopy study of catalyst degradation under electrochemical treatment. J Power Sources 185, 734–739.CrossRefGoogle Scholar
Prestat, E., Smith, M., Janssen, A., Slater, T.J.A., Camargo, P.H.C., Kulzick, M.A., Burke, M.G., Haigh, S.J. & Zaluzec, N.J. (2015). XEDS and EELS in the TEM at atmospheric pressure and high temperature. Microsc Microanal 21(Suppl 3), 247–248.CrossRefGoogle Scholar
Saka, H. (2008). In-situ high resolution observation of solid-solid, solid-liquid and solid-gas reactions. In In-Situ Electron Microscopy at High Resolution, Banhart, F. (Eds.), pp. 49–114. Singapore: World Scientific Publishing C. Pte. Ltd.CrossRefGoogle Scholar
Sharma, R. & Weiss, K. (1998). Development of a TEM to study in situ structural and chemical changes at atomic level during gas solid interaction at elevated temperatures. Microsc Res 42, 270–280.3.0.CO;2-U>CrossRefGoogle ScholarPubMed
Tinnemans, S.J., Mesu, J.G., Kervinen, K., Visser, T., Niijhuis, T.A., Beale, A.M., Keller, D.E., Van Der Eerden, A.M.J. & Weckhuysen, B.M. (2006). Combining operando techniques in one spectroscopic-reaction cell: New opportunities for elucidating the active site and related reaction mechanism in catalyst. Catalysis Today 113, 3–15.CrossRefGoogle Scholar
Weckhuysen, B.M. (2003). Determining the active site in a catalytic process: Operando spectroscopy is more than a buzzword. Phys Chem Chem Phys 5, 4351–4360.CrossRefGoogle Scholar
Yaguchi, T., Shimizu, T. & Kamino, T. (2014). ETEM technique for development of energy-related new materials. Kenbikyo 60, 217–225.Google Scholar