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Angular Dependence of the Ion-Induced Secondary Electron Emission for He+ and Ga+ Beams

Published online by Cambridge University Press:  16 June 2011

Vincenzo Castaldo*
Affiliation:
Department of Applied Science, Delft University of Technology, Lorentzweg 1, Delft, Zuid-holland 2628CJ, The Netherlands
Josephus Withagen
Affiliation:
Department of Applied Science, Delft University of Technology, Lorentzweg 1, Delft, Zuid-holland 2628CJ, The Netherlands
Cornelius Hagen
Affiliation:
Department of Applied Science, Delft University of Technology, Lorentzweg 1, Delft, Zuid-holland 2628CJ, The Netherlands
Pieter Kruit
Affiliation:
Department of Applied Science, Delft University of Technology, Lorentzweg 1, Delft, Zuid-holland 2628CJ, The Netherlands
Emile van Veldhoven
Affiliation:
TNO Science and Industry, Stieltjesweg 1, Delft, Zuid-holland 2628CK, The Netherlands
*
Corresponding author. E-mail: [email protected]
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Abstract

In recent years, novel ion sources have been designed and developed that have enabled focused ion beam machines to go beyond their use as nano-fabrication tools. Secondary electrons are usually taken to form images, for their yield is high and strongly dependent on the surface characteristics, in terms of chemical composition and topography. In particular, the secondary electron yield varies characteristically with the angle formed by the beam and the direction normal to the sample surface in the point of impact. Knowledge of this dependence, for different ion/atom pairs, is thus the first step toward a complete understanding of the contrast mechanism in scanning ion microscopy. In this article, experimentally obtained ion-induced secondary electron yields as a function of the incidence angle of the beam on flat surfaces of Al and Cr are reported, for usual conditions in Ga+ and He+ microscopes. The curves have been compared with models and simulations, showing a good agreement for most of the angle range; deviations from the expected behavior are addressed and explanations are suggested. It appears that the maximum value of the ion-induced secondary electron yield is very similar in all the studied cases; the yield range, however, is consistently larger for helium than for gallium, which partially explains the enhanced topographical contrast of helium microscopes over the gallium focused ion beams.

Type
Helium Ion Microscopy
Copyright
Copyright © Microscopy Society of America 2011

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References

REFERENCES

Bell, D. (2009). Contrast mechanisms and image formation in helium ion microscopy. Microsc Microanal 15, 147153.CrossRefGoogle ScholarPubMed
Castaldo, V., Hagen, C.W., Kruit, P., van Veldhoven, E. & Maas, D. (2009). On the influence of the sputtering in determining the resolution of a scanning ion microscope. J Vac Sci Technol B 27(6), 31963202.CrossRefGoogle Scholar
Castaldo, V., Hagen, C.W., Rieger, B. & Kruit, P. (2008). Sputtering limits versus signal-to-noise limits in the observation of Sn-balls in a Ga+ microscope. J Vac Sci Technol B 26(6), 21072115.CrossRefGoogle Scholar
Ferron, J., Alonso, E., Baragiola, R. & Oliva-Florio, A. (1981). Dependence of ion-electron emission from clean metals on the incidence angle of the projectile. Phys Rev B 24(8), 44124419.CrossRefGoogle Scholar
Giannuzzi, L.A., Utlaut, M. & Scheinfein, M. (2008). Relative contrast in ion and electron induced secondary electron images. Microsc Microanal 14(S2), 11881189 (CD-ROM).CrossRefGoogle Scholar
Griffin, B.J. & Joy, D. (2008). Variation of Rutherford backscattered ion and ion-induced secondary electron yield with atomic number in the “Orion” scanning helium ion microscope. Microsc Microanal 14(S2), 11901191 (CD-ROM).CrossRefGoogle Scholar
Hagstrum, H.D. (1954a). Auger ejection of electrons from tungsten by noble gas ions. Phys Rev 96(2), 325335.CrossRefGoogle Scholar
Hagstrum, H.D. (1954b). Theory of Auger ejection of electrons from metals by ions. Phys Rev 96(2), 336365.CrossRefGoogle Scholar
Hill, R., Notte, J. & Ward, B. (2008). The ALIS He ion source and its application to high resolution microscopy. Physics Procedia 1, 135141.CrossRefGoogle Scholar
Ishitani, T. & Ohya, K. (2003). Comparison in spatial spreads of secondary electron information between scanning ion and scanning electron microscopy. Scanning 25(4), 201209.CrossRefGoogle ScholarPubMed
Kempshall, B.W., Schwarz, S.M., Prenitzer, B.I., Giannuzzi, L.A., Irwin, R.B. & Stevie, F.A. (2001). Ion channeling effects on the focused ion beam milling of Cu. J Vac Sci Technol B 19(3), 749754.CrossRefGoogle Scholar
Ogawa, S., Thompson, W., Stern, L., Scipioni, L., Notte, J., Farkas, L. & Barriss, L. (2010). Helium ion secondary electron mode microscopy for interconnect material imaging. Jpn J Appl Phys 49(4), 04DB12.CrossRefGoogle Scholar
Ohya, K. & Ishitani, T. (2003). Comparative study of depth and lateral distributions of electron excitation between scanning ion and scanning electron microscopes. J Electron Microsc 52(3), 291298.CrossRefGoogle ScholarPubMed
Ohya, K. & Kawata, J. (1994). Monte Carlo study of incident-angle dependence of ion-induced kinetic electron emission from solids. Nucl Instrum Meth B 90(1-4), 552555.CrossRefGoogle Scholar
Orloff, J. (1993). High-resolution focused ion beams. Rev Sci Instrum 64(5), 11051130.CrossRefGoogle Scholar
Orloff, J., Swanson, L.W. & Utlaut, M. (1996). Fundamental limits to imaging resolution for focused ion beams. J Vac Sci Technol B 14(6), 37593763.CrossRefGoogle Scholar
Orloff, J., Utlaut, M. & Swanson, L.W. (2003). High Resolution Focused Ion Beams. Boston, MA: Kluwer Academic/Plenum Publishers.CrossRefGoogle Scholar
Ramachandra, R., Griffin, B. & Joy, D. (2009). A model of secondary electron imaging in the helium ion scanning microscope. Ultramicroscopy 109(6), 748757.CrossRefGoogle Scholar
Seiler, H. (1983). Secondary electron emission in the scanning electron microscope. J Appl Phys 54(11), R1R18.CrossRefGoogle Scholar
Seliger, R.L., Ward, J.W., Wang, V. & Kubena, R.L. (1979). A high-intensity scanning ion probe with submicrometer spot size. Appl Phys Lett 34(5), 310312.CrossRefGoogle Scholar
Sternglass, E. (1957). Theory of secondary electron emission by high-speed ions. Phys Rev 108(1), 112.CrossRefGoogle Scholar
Svensson, B., Holmen, G. & Buren, A.A. (1981). Angular dependence of the ion-induced secondary-electron yield from solids. Phys Rev B 24(7), 37493755.CrossRefGoogle Scholar
Tondare, V.N. (2005). Quest for high brightness, monochromatic noble gas ion sources. J Vac Sci Technol A 23(6), 14981508.CrossRefGoogle Scholar
Ward, B., Notte, J.A. & Economou, N.P. (2006). Helium ion microscope: A new tool for nanoscale microscopy and metrology. J Vac Sci Technol B 24(6), 28712874.CrossRefGoogle Scholar
Yamamura, Y., Mossner, C. & Oechsner, H. (1987). The bombarding-angle dependence of sputtering yields under various surface conditions. Radiat Effects 103, 2543.CrossRefGoogle Scholar
Ziegler, J.F., Biersack, J.P. & Littmark, U. (1985). The Stopping and Range of Ions in Solids. New York: Pergamon Press (1996 revised Ed.). Information for SRIM and TRIM available atwww.srim.org (the TRIM code is available for free download).Google Scholar