Published online by Cambridge University Press: 02 July 2020
Ordered assembly of hollow structures of silica and carbon have drawn much attention recently because of their applications in low-loss dielectrics, catalysis, filtering and photonics. The structure is ordered on the length-scale of the template spheres and the pore sizes are in submicron to micron range. Alternatively, ordered porous silica with much smaller pore sizes in nanosize range (< 30 nm), produced deliberately by introducing surfactant, has also been processed, in which the porosity is created by co-polymers. In this research, a new silica nanostructure with double length-scale ordered porosities was processed, one being at the submicron scale of hollow spheres created by a template of polystyrene (PS), and the other at nano-scale created by self-assembled co-polymers.
Typical processing route includes three steps. Firstly, the ordered template of PS was created. The as-received PS with mean particle size of 203 nm was used as the raw material.
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[3] Thanks to NSF DMR-9733160 for support and Dr.Xin, Y.B.for assistance during experiment.Google Scholar