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Double Length-Scale Ordered Nanoporous Silica

Published online by Cambridge University Press:  02 July 2020

J.S. Yin
Affiliation:
School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA30332
Z.L. Wang
Affiliation:
School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA30332
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Extract

Ordered assembly of hollow structures of silica and carbon have drawn much attention recently because of their applications in low-loss dielectrics, catalysis, filtering and photonics. The structure is ordered on the length-scale of the template spheres and the pore sizes are in submicron to micron range. Alternatively, ordered porous silica with much smaller pore sizes in nanosize range (< 30 nm), produced deliberately by introducing surfactant, has also been processed, in which the porosity is created by co-polymers. In this research, a new silica nanostructure with double length-scale ordered porosities was processed, one being at the submicron scale of hollow spheres created by a template of polystyrene (PS), and the other at nano-scale created by self-assembled co-polymers.

Typical processing route includes three steps. Firstly, the ordered template of PS was created. The as-received PS with mean particle size of 203 nm was used as the raw material.

Type
Future of Microscopy: Ceramics, Composites, and Cement
Copyright
Copyright © Microscopy Society of America

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References

[1] Kresge, C.T.et al., Nature 359 (1992) 710.CrossRefGoogle Scholar

[2] J.S., Yin and Z.L., Wang, Appl. Phys. Lett., 1999, submitted.Google Scholar

[3] Thanks to NSF DMR-9733160 for support and Dr.Xin, Y.B.for assistance during experiment.Google Scholar