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Photochromism in spiropyran impregnated fluorinated mesoporous organosilicate films

Published online by Cambridge University Press:  03 March 2011

Jae Young Bae ,
Ji-In Jung  and
Byeong-Soo Bae
Jae Young Bae
Affiliation:
Laboratory of Optical Materials and Coating (LOMC), Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 305-701, Republic of Korea
Ji-In Jung
Affiliation:
Laboratory of Optical Materials and Coating (LOMC), Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 305-701, Republic of Korea
Byeong-Soo Bae*
Affiliation:
Laboratory of Optical Materials and Coating (LOMC), Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 305-701, Republic of Korea
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

Fluorinated mesoporous organosilicate films were synthesized by sol-gel spin-coating on a quartz substrate using (heptadecafluorodecyl)trimethoxysilane, tetramethylorthosilicate, and n-cetyltrimethylammonium chloride as the fluoro-precursor, silica source, and supramolecular template, respectively. The photochromism efficiency of photochromic dyes (spiropyran) increases in the order non-porous < hexagonal mesoporous < fluorinated mesoporous organosilicate films. The relatively high efficiency of the photochromism of spiropyran in fluorinated mesoporous organosilicate films suggests that such films are promising materials for applications as optical shutters and light modulators.

Keywords

Sol-gelThin filmPhotochemical
Type
Articles
Information
Journal of Materials Research , Volume 19 , Issue 8 , August 2004 , pp. 2503 - 2509
Copyright
Copyright © Materials Research Society 2004

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References

REFERENCES

1.Kresge, C.T., Leonowicz, M.E., Roth, W.J., Vartuli, J.C. and Beck, J.S.: Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism. Nature 359, 710 (1992).CrossRefGoogle Scholar
2.Ying, J.Y., Mehnert, C.P. and Wong, M.S.: Synthesis and applications of supramolecular-templated mesoporous materials. Angew. Chem. Int. Ed. Engl. 38, 56 (1999).3.0.CO;2-E>CrossRefGoogle Scholar
3.Ciesla, U. and Schüth, F.: Ordered mesoporous materials. Microporous. Mesoporous. Mater. 27, 131 (1999).CrossRefGoogle Scholar
4.Yang, C.M. and Chao, K.J.: Functionalization of molecularly templated mesoporous silica. J. Chin. Chem. Soc. 49, 883 (2002).CrossRefGoogle Scholar
5.Ogawa, M.: Formation of novel oriented transparent films of layered silica-surfactant nanocomposites. J. Am. Chem. Soc. 116, 7941 (1994).CrossRefGoogle Scholar
6.Lu, Y., Ganguli, R., Drewien, C.A., Anderson, M.T., Brinker, C.J., Gong, W., Guo, Y., Soyez, H., Dunn, B., Huang, M.H. and Zink, J.I.: Continuous formation of supported cubic hexagonal mesoporous films by sol-gel dip-coating. Nature 389, 364 (1997).CrossRefGoogle Scholar
7.Brinker, C.J., Lu, Y., Sellinger, A. and Fan, H.: Evaporation-induced self-assembly: nanostructures made easy. Adv. Mater. 11, 579 (1999).3.0.CO;2-R>CrossRefGoogle Scholar
8.Ogawa, M. and Masukawa, N.: Preparation of transparent thin films of lamellar, hexagonal and cubic silica-surfactant mesostructured materials by rapid solvent evaporation methods. Microporous. Mesoporous. Mater. 38, 35 (2000).CrossRefGoogle Scholar
9.Bae, J.Y., Jung, J.I., Park, O.H., Bae, B.S., Ranjit, K.T. and Kevan, L.: Synthesis and characterization of mesoporous silica films by spin-coating on silicon: Photoionization of methylphenothiazine and photoluminescence of erbium 8-hydroxyquinolinate in mesoporous silica films. Stud. Surf. Sci. Catal. 146, 65 (2003).CrossRefGoogle Scholar
10.Lebeau, B., Marichal, C., Mirjol, A., de Soler-Illia, G.J. A.A., Buestrich, R., Popall, M., Mazerolles, L. and Sanchez, C.: Synthesis of highly ordered mesoporous hybrid silica from aromatic fluorinated organosilane precursors. New J. Chem. 27, 166 (2003).CrossRefGoogle Scholar
11.Stein, A., Melde, B.J. and Schroden, R.C.: Hybrid inorganic-organic mesoporous silicates-nanoscopic reactors coming of age. Adv. Mater. 12, 1403 (2000).3.0.CO;2-X>CrossRefGoogle Scholar
12.Sayari, A. and Hamoudi, S.: Periodic mesoporous silica-based organic-inorganic nanocomposite materials. Chem. Mater. 13, 3151 (2001).CrossRefGoogle Scholar
13.Orenstein, M., Katriel, J. and Speiser, S.: Optical bistability in molecular systems exhibiting nonlinear absorption. Phys. Rev. A 35, 2175 (1987).CrossRefGoogle ScholarPubMed
14.Matias, I.R., Lopez-Amo, M., Fiksman, G., Oton, J.M., Levy, D. and Monte, F. Del: Dynamic behavior of sol-gel gel-glass based thermochromic material applied toward development of practical optical temperature sensors. Opt. Eng. 37, 2620 (1998).CrossRefGoogle Scholar
15.Wirnsberger, G., Scott, B.J., Chmelka, B.F. and Stucky, G.D.: Fast response photochromic mesostructures. Adv. Mater. 12, 1450 (2000).3.0.CO;2-4>CrossRefGoogle Scholar
16.Cran, J.C. and Guglielmetti, R.J.: Organic Photochromic and Thermochromic Compounds (Plenum Press, New York and London, 1999), p. 11.Google Scholar
17.Oliver, S., Kuperman, A., Coombs, N., Louth, A. and Ozin, G.A.: Lamellar aluminophosphates that mimic radiolaria and diatom skeletons. Nature 378, 47 (1995).CrossRefGoogle Scholar
18.Silverstein, R.M., Bassler, G.C., and Morrill, T.C., Spectrometric Identification of Organic Compounds (John Wiley & Sons Press, New York, 1991), p. 130.Google Scholar
19.Clarson, S.J. and Semyen, J.A.: Siloxane Polymers (PTR Prentice Hall, Eaglewood Cliffs, NJ, 1933), p. 327.Google Scholar
20.Flannery, J.B. Jr.: The photo- and thermochromic transients from substituted 1′,3′,3′-trimethylindolinobenzospiropyrans. J. Am. Chem. Soc. 90, 5660 (1968).CrossRefGoogle Scholar
21.Park, O.H., Seo, S.Y., Jung, J.I., Bae, J.Y. and Bae, B.S.: Photoluminescence of mesoporous silica films impregnated with an erbium complex. J. Mater. Res. 18, 1039 (2003).CrossRefGoogle Scholar
22.Bae, J.Y., Park, O.H., Jung, J.I., Ranjit, K.T. and Bae, B.S.: Photoionization of methylphenothiazine and photoluminescence of erbium 8-hydroxyquinolinate in transparent mesoporous silica films by spin-coating on silicon. Microporous. Mesoporous. Mater. 67, 265 (2004).CrossRefGoogle Scholar
23.Levy, D. and Avnir, D.: Effects of the changes in the properties of silica cage along the gel/xerogel transition on the photochromic behavior of trapped spiropyrans. J. Phys. Chem. 92, 4734 (1988).CrossRefGoogle Scholar
24.Hou, L., Hoffman, B., Schmidt, H. and Menning, M.: Effect on heat treatment and additives on the photochromic and mechanical properties of sol-gel derived photochromic coatings containing spirooxazine. J. Sol-Gel Sci. Technol. 8(1997).CrossRefGoogle Scholar