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PbSe nanocrystal/conducting polymer solar cells with an infrared response to 2 micron

Published online by Cambridge University Press:  31 January 2011

Xiaomei Jiang ,
Richard D. Schaller ,
Sergey B. Lee ,
Jeffrey M. Pietryga ,
Victor I. Klimov  and
Anvar A. Zakhidov
Xiaomei Jiang*
Affiliation:
Nanotech Institute, University of Texas at Dallas, Richardson, Texas 75083; and Physics Department, University of South Florida, Tampa, Florida 33620
Richard D. Schaller
Affiliation:
Chemistry Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545
Sergey B. Lee
Affiliation:
Nanotech Institute, University of Texas at Dallas, Richardson, Texas 75083; and Plextronics, Inc., Pittsburgh, Pennsylvania 15238
Jeffrey M. Pietryga
Affiliation:
Chemistry Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545
Victor I. Klimov
Affiliation:
Chemistry Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545
Anvar A. Zakhidov
Affiliation:
Nanotech Institute, University of Texas at Dallas, Richardson, Texas 75083; and Physics Department, University of Texas at Dallas, Richardson, Texas 75083
*
a)e-mail: [email protected]
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Abstract

We investigated the photovoltaic response of nanocomposites made of colloidal, infrared-sensitive, PbSe nanocrystals (NCs) of various sizes and conjugated polymers of either regioregular poly (3-hexylthiophene) (RR-P3HT) or poly- (2-methoxy-5-(2-ethylhexoxy)-1,4-phenylene vinylene) (MEH-PPV). The conduction and valence energy levels of PbSe NCs were determined by cyclic voltammetry and revealed type II heterojunction alignment with respect to energy levels in RR-P3HT for smaller NC sizes. Devices composed of NCs and RR-P3HT show good diode characteristics and sizable photovoltaic response in a spectral range from the ultraviolet to the infrared. Using these materials, we have observed photovoltaic response at wavelengths as far to the infrared as 2 μm (0.6 eV), which is desirable due to potential benefits of carrier multiplication (or multi-exciton generation) from a single junction photovoltaic. Under reverse bias, the devices also exhibit good photodiode responses over the same spectral region.

Keywords

PhotovoltaicPolymerNanostructure
Type
Articles
Information
Journal of Materials Research , Volume 22 , Issue 8 , August 2007 , pp. 2204 - 2210
Copyright
Copyright © Materials Research Society 2007

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References

REFERENCES

1Murray, C.B., Norris, D.J.Bawendi, M.G.: Synthesis and characterization of nearly monodisperse CdE (E = sulfur, selenium, tellurium) semiconductor nanocrystallites. J. Am. Chem. Soc. 115, 8706 1993CrossRefGoogle Scholar
2Schaller, R.D.Klimov, V.I.: High-efficiency carrier multiplication in PbSe nanocrystals: Implications for solar energy conversion. Phys. Rev. Lett. 92, 186601 2004CrossRefGoogle ScholarPubMed
3Schaller, R.D., Petruska, M.A.Klimov, V.I.: Effect of electronic structure on carrier multiplication efficiency: Comparative study of PbSe and CdSe nanocrystals. Appl. Phys. Lett. 87, 253102 2005CrossRefGoogle Scholar
4Shockley, W.Queisser, H.J.: Detailed balance limit of efficiency of P–N junction solar cells. J. Appl. Phys. 32, 510 1961CrossRefGoogle Scholar
5Klimov, V.I.: Detailed-balance power conversion limits of nanocrystal-quantum-dot solar cells in the presence of carrier multiplication. Appl. Phys. Lett. 89, 123118 2006CrossRefGoogle Scholar
6Greenham, N.C., Peng, X.Alivisatos, A.P.: Charge separation and transport in conjugated-polymer/semiconductor-nanocrystal composites studied by photoluminescence quenching and photoconductivity. Phys. Rev. B 54, 17628 1996CrossRefGoogle ScholarPubMed
7Ginger, D.S.Greenham, N.C.: Charge injection and transport in films of CdSe nanocrystals. J. Appl. Phys. 87, 1361 2000CrossRefGoogle Scholar
8Huynh, W.U., Dittmer, J.J.Alivisatos, A.P.: Hybrid nanorod-polymer solar cells. Science 295, 2425 2002CrossRefGoogle ScholarPubMed
9Huynh, W.U., Dittmer, J.J., Libby, W.C., Whiting, G.L.Alivisatos, A.P.: Controlling the morphology of nanocrystal-polymer composites for solar cells. Adv. Funct. Mater. 13, 73 2003CrossRefGoogle Scholar
10Liu, J., Tanaka, T., Sivula, K., Alivisatos, A.P.Frechet, J.M.J.: Employing end-functional polythiophene to control the morphology of nanocrystal-polymer composites in hybrid solar cells. J. Am. Chem. Soc. 126, 6550 2004CrossRefGoogle ScholarPubMed
11Sun, B., Marx, E.Greenham, N.C.: Photovoltaic devices using blends of branched CdSe nanoparticles and conjugated polymers. Nano Lett. 3, 961 2003CrossRefGoogle Scholar
12Landsberg, P.: Recombination in Semiconductors Cambridge Univ. Press Cambridge, UK 1991Google Scholar
13Next Generation Photovoltaics: High Efficiency through Full Spectrum Utilization edited by A. Marti and A. Luque IOP Publishing Bristol 2004Google Scholar
14Murray, C.B., Sun, S.H., Gaschler, W., Doyle, H., Betley, T.A.Kagan, C.R.: Colloidal synthesis of nanocrystals and nanocrystal superlattices. IBM J. Res. Dev. 45, 47 2001CrossRefGoogle Scholar
15Pietryga, J.M., Schaller, R.D., Werder, D., Stewart, M.H., Klimov, V.I., Hollingsworth, J.A.: Pushing the band gap envelope: Mid-infrared emitting colloidal PbSe quantum dots. J. Am. Chem. Soc. 126, 11752 2004CrossRefGoogle ScholarPubMed
16Guzelian, A.A., Banin, U., Kadavanich, A.V., Peng, X.Alivisatos, A.P.: Colloidal chemical synthesis and characterization of InAs nanocrystal quantum dots. Appl. Phys. Lett. 69, 1432 1996CrossRefGoogle Scholar
17Rogach, A.L., Harrison, M.T., Kershaw, S.V., Kornowski, A., Burt, M.G., Eychmuller, A.Weller, H.: Colloidally prepared CdHgTe and HgTe quantum dots with strong near-infrared luminescence. Phys. Status Solidi 224, 153 20013.0.CO;2-3>CrossRefGoogle Scholar
18McDonald, S.A., Konstantatos, G., Zhang, S., Cyr, P.W., Klem, E.J.D., Levina, L.Sargent, E.H.: Solution-processed PbS quantum dot infrared photodetectors and photovoltaics. Nat. Mater. 4, 138 2005CrossRefGoogle ScholarPubMed
19Maria, A., Cyr, P.W., Klem, E.J.D., Levina, L.Sargent, E.H.: Solution-processed infrared photovoltaic devices with >10% monochromatic internal quantum efficiency. Appl. Phys. Lett. 87, 213112 2005CrossRefGoogle Scholar
20Watt, A.A.R., Blake, D., Warner, J.H., Thomsen, E.A., Tavenner, E.L., Rubinsztein-Dunlop, H.Meredith, P.: Lead sulfide nanocrystal: Conducting polymer solar cells. J. Phys. D 38, 2006 2005CrossRefGoogle Scholar
21Zhang, S., Cyr, P.W., McDonald, S.A., Konstantatos, G.Sargent, E.H.: Enhanced infrared photovoltaic efficiency in PbS nanocrystal/semiconducting polymer composites: 600-fold increase in maximum power output via control of the ligand barrier. Appl. Phys. Lett. 87, 233101 2005CrossRefGoogle Scholar
22Plass, R., Pelet, S., Krueger, J., Gratzel, M.Bach, U.: Quantum dot sensitization of organic-inorganic hybrid solar cells. J. Phys. Chem. B 106, 7578 2002CrossRefGoogle Scholar
23Jiang, X., Lee, S.B., Altfeder, I.B., Zakhidov, A.A., Schaller, R.D., Pietryga, J.M.Klimov, V.I.: Nanocomposite solar cells based on conjugated polymer/PbSe quantum dot. Proc. SPIE 5938, 59381F-1 2005Google Scholar
24Cui, D., Xu, J., Zhu, T., Paradee, G., Ashok, S.Gerhold, M.: Harvest of near infrared light in PbSe nanocrystal-polymer hybrid photovoltaic cells. Appl. Phys. Lett. 88, 183111 2006CrossRefGoogle Scholar
25Qi, D., Fischbein, M., Drndic, M.Selmic, S.: Efficient polymer-nanocrystal quantum-dot photodetectors. Appl. Phys. Lett. 86, 093103 2005CrossRefGoogle Scholar
26Wehrenberg, B.L.Guyot-Sionnest, P.: Electron and hole injection in PbSe quantum dot films. J. Am. Chem. Soc. 125, 7806 2003CrossRefGoogle ScholarPubMed
27Haram, S.K., Quinn, B.M.Bard, A.J.: Electrochemistry of CdS nanoparticles: A correlation between optical and electrochemical band gaps. J. Am. Chem. Soc. 123, 8860 2001CrossRefGoogle ScholarPubMed
28Campbell, I.H., Hagler, T.W., Smith, D.L.Ferraris, J.P.: Direct measurement of conjugated polymer electronic excitation energies using metal/polymer/metal structures. Phys. Rev. Lett. 76, 1900 1996CrossRefGoogle ScholarPubMed
29Liu, Y., Summers, M.A., Edder, C., Frechet, J.M.J.McGehee, M.D.: Using resonance energy transfer to improve exciton harvesting in organic-inorganic hybrid photovoltaic cells. Adv. Mater. 17, 2960 2005CrossRefGoogle Scholar
30Solomeshch, O., Kigel, A., Saschiuk, A., Medvedev, V., Aharoni, A., Razin, A., Eichen, Y., Banin, U., Lifshitz, E.Tessler, N.: Photoelectronic properties of polymer-nanocrystal composites active at near-infrared wavelengths. J. Appl. Phys. 98, 074310 2005CrossRefGoogle Scholar
31Efros, A.L.Shklovskii, B.I.: Coulomb gap and low temperature conductivity of disordered systems. J. Phys. C 8, L49 1975CrossRefGoogle Scholar
32Schaller, R.D., Agranovich, V.M.Klimov, V.I.: High-efficiency carrier multiplication through direct photogeneration of multi-excitons via virtual single-exciton states. Nature Phys. 1, 189 2005CrossRefGoogle Scholar
33Schaller, R.D., Sykora, M., Pietryga, J.M.Klimov, V.I.: Seven excitons at a cost of one: Redefining the limits for conversion efficiency of photons into charge carriers. Nano Lett. 6, 424 2006CrossRefGoogle Scholar
34Klimov, V.I., Mikhailovsky, A.A., McBranch, D.W., Leatherdale, C.A.Bawendi, M.G.: Quantization of multiparticle auger rates in semiconductor quantum dots. Science 287, 1011 2000CrossRefGoogle ScholarPubMed
35Evans, J.E., Springer, K.W.Zhang, J.Z.: Femotosecond studies of interparticle electron transfer on a coupled CdS–TiO2 colloidal system. J. Chem. Phys. 101, 6222 1994CrossRefGoogle Scholar
36Blackburn, J.L., Selmarten, D.C.Nozik, A.J.: Electron transfer dynamics in quantum dot/titanium dioxide composites formed by in situ chemical bath deposition. J. Phys. Chem. B 107, 14154 2003CrossRefGoogle Scholar
37Htoon, H., Hollingsworth, J.A., Dickerson, R.Klimov, V.I.: Effect of zero- to one-dimensional transformation on multiparticle auger recombination in semiconductor quantum rods. Phys. Rev. Lett. 91, 227401 2003CrossRefGoogle ScholarPubMed
38Huynh, W.U., Dittmer, J.J.Alivisatos, A.P.: Hybrid nanorod-polymer solar cells. Science 295, 2425 2002CrossRefGoogle ScholarPubMed
39Talapin, D.V.Murray, C.B.: PbSe Nanocrystal solids for n- and p-channel thin film field-effect transistor. Science 310, 86 2005CrossRefGoogle Scholar