Hostname: page-component-586b7cd67f-tf8b9 Total loading time: 0 Render date: 2024-11-28T11:32:44.062Z Has data issue: false hasContentIssue false

Electrocoalescence of a pair of conducting drops in an insulating oil

Published online by Cambridge University Press:  26 November 2018

Vikky Anand
Affiliation:
Department of Chemical Engineering, Indian Institute of Technology Bombay, Powai, Mumbai 400 076, India
Subhankar Roy
Affiliation:
Department of Chemical Engineering, Indian Institute of Technology Bombay, Powai, Mumbai 400 076, India
Vijay M. Naik
Affiliation:
Department of Chemical Engineering, Indian Institute of Technology Bombay, Powai, Mumbai 400 076, India
Vinay A. Juvekar
Affiliation:
Department of Chemical Engineering, Indian Institute of Technology Bombay, Powai, Mumbai 400 076, India
Rochish M. Thaokar*
Affiliation:
Department of Chemical Engineering, Indian Institute of Technology Bombay, Powai, Mumbai 400 076, India
*
Email address for correspondence: [email protected]

Abstract

The effect of an electric field on the coalescence of two water drops suspended in an insulating oil is investigated. We report four new results. (i) The cone angle for the non-coalescence of drops can be significantly smaller (as small as $19^{\circ }$) than the value of $30.8^{\circ }$ reported by Bird et al. (Phys. Rev. Lett., vol. 103 (16), 2009, 164502). (ii) A surprising observation of the dependence of the mode of coalescence/non-coalescence on the type of insulating oil is seen. A cone–cone mode for silicone oil is observed as against cone–dimple mode for castor oil. (iii) The critical capillary number for non-coalescence decreases with increase in the conductivity of the droplet phase. (iv) Systematic experiments prove that the apparent bridge during non-coalescence is indeed transitory and not permanent, as reported elsewhere. Theoretical calculations using analytical theory and the boundary integral method explain the formation of the cone–dimple mode as well as the transitory bridge length. The numerical calculation and thereby the physical mechanism to explain the occurrence of very small non-coalescence angles as well as the dependence of the phenomenon on the conductivity of the insulating oil and the water droplets remain unexplained.

Type
JFM Papers
Copyright
© 2018 Cambridge University Press 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Allan, R. S. & Mason, S. G. 1961 Effects of electric fields on coalescence in liquid + liquid systems. Trans. Faraday Soc. 57, 20272040.Google Scholar
Anand, V., Vashishtha, M., Shown, B., Patidar, P., Malhotra, A., Ghosh, S., Jaguste, S., Naik, V. M., Thaokar, R. M. & Juvekar, V. A. 2018 Interrelationship between electrocoalescence and interfacial tension in a high acidity crude: effect of pH and nature of alkalinity. Colloids 555, 728735.Google Scholar
Aryafar, H. & Kavehpour, P. 2007 Electrocoalescence. Phys. Fluids 19 (9), 091107.Google Scholar
Atten, P. 1993 Electrocoalescence of water droplets in an insulating liquid. J. Electrostat. 30, 259269.Google Scholar
Bartlett, C. T., Généro, G. A. & Bird, J. C. 2015 Coalescence and break-up of nearly inviscid conical droplets. J. Fluid Mech. 763, 369385.Google Scholar
Bird, J. C., Ristenpart, W. D., Belmonte, A. & Stone, H. A. 2009 Critical angle for electrically driven coalescence of two conical droplets. Phys. Rev. Lett. 103 (16), 164502.Google Scholar
Cottrell, F. G. & Speed, J. B.1911 Separating and collecting particles of one liquid suspended in another liquid. US Patent 987,115.Google Scholar
Davis, M. H. 1964 Two charged spherical conductors in a uniform electric field: forces and field strength. Q. J. Mech. Appl. Maths 17 (4), 499511.Google Scholar
Guo, C. & He, L. 2014 Coalescence behaviour of two large water-drops in viscous oil under a dc electric field. J. Electrostat. 72 (6), 470476.Google Scholar
Hamlin, B. S., Creasey, J. C. & Ristenpart, W. D. 2012 Electrically tunable partial coalescence of oppositely charged drops. Phys. Rev. Lett. 109 (9), 094501.Google Scholar
Helmensdorfer, S. & Topping, P. 2013 Bouncing of charged droplets: an explanation using mean curvature flow. Europhys. Lett. 104 (3), 34001.Google Scholar
Khair, A. S. 2013 Electrostatic forces on two almost touching nonspherical charged conductors. J. Appl. Phys. 114 (13), 134906.Google Scholar
Less, S. & Vilagines, R. 2012 The electrocoalescers’ technology: advances, strengths and limitations for crude oil separation. J. Petrol. Sci. Engng 81, 5763.Google Scholar
Lu, J., Fang, S. & Corvalan, C. M. 2016 Coalescence dynamics of viscous conical drops. Phys. Rev. E 93 (2), 023111.Google Scholar
Mhatre, S., Deshmukh, S. & Thaokar, R. M. 2015 Electrocoalescence of a drop pair. Phys. Fluids 27 (9), 092106.Google Scholar
Mhatre, S. & Thaokar, R. 2015 Electrocoalescence in non-uniform electric fields: an experimental study. Chem. Engng Process.: Process Intensification 96, 2838.Google Scholar
Owe Berg, T. G., Fernish, G. C. & Gaukler, T. A. 1963 The mechanism of coalescence of liquid drops. J. Atmos. Sci. 20 (2), 153158.Google Scholar
Pearce, C. A. R. 1954 The mechanism of the resolution of water-in-oil emulsions by electrical treatment. Brit. J. Appl. Phys. 5 (4), 136143.Google Scholar
Ristenpart, W. D., Bird, J. C., Belmonte, A., Dollar, F. & Stone, H. A. 2009 Non-coalescence of oppositely charged drops. Nature 461 (7262), 377380.Google Scholar
Thiam, A. R., Bremond, N. & Bibette, J. 2009 Breaking of an emulsion under an ac electric field. Phys. Rev. Lett. 102 (18), 188304.Google Scholar

Anand et al. supplementary movie 1

Coalescence of Milli-Q water drops in silicone oil. Capillary number (Ca) = 0.033, frequency = 50 Hz, Cone angle = 20o. The video was captured at 10000 frames/sec and slowed down to 30 frames/sec.

Download Anand et al. supplementary movie 1(Video)
Video 5.5 MB

Anand et al. supplementary movie 2

Non-coalescence of Milli-Q water drops in silicone oil. Capillary number (Ca) = 0. 0.09, frequency = 50 Hz, Cone angle = 22o. The video was captured at 10000 frames/sec and slowed down to 10 frames/sec.

Download Anand et al. supplementary movie 2(Video)
Video 1.5 MB

Anand et al. supplementary movie 3

Coalescence of Milli-Q water drops in castor oil. Capillary number (Ca) = 0.063, frequency = 50 Hz. The video was captured at 10000 frames/sec and slowed down to 30 frames/sec.

Download Anand et al. supplementary movie 3(Video)
Video 5.5 MB

Anand et al. supplementary movie 4

Non-coalescence of Milli-Q water drops in castor oil. Capillary number (Ca) = 0.10, frequency = 50 Hz. The video was captured at 10000 frames/sec and slowed down to 30 frames/sec.

Download Anand et al. supplementary movie 4(Video)
Video 2.8 MB

Anand et al. supplementary movie 5

Interaction and transient bridge formation between two Milli-Q water drops in silicone oil. Capillary number (Ca) = 0.066, frequency = 5000 Hz. The video was captured at 41000 frames/sec and slowed down to 5 frames/sec.

Download Anand et al. supplementary movie 5(Video)
Video 133.2 KB
Supplementary material: PDF

Anand et al. supplementary material

Supplementary information

Download Anand et al. supplementary material(PDF)
PDF 149.8 KB