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Clay-Organic Complexes as a Cementing Agent in the Arahama Sand Dune, Japan

Published online by Cambridge University Press:  02 April 2024

Kazue Tazaki ,
S. Kimura ,
T. Yoshimura ,
J. Akai  and
W. S. Fyfe
Kazue Tazaki
Affiliation:
Department of Geology, Shimane University, Nishikawatsu, Matsue, Shimane 690, Japan
S. Kimura
Affiliation:
Toyosaka High School, Toyosaka, Niigata 950-33, Japan
T. Yoshimura
Affiliation:
Department of Geology and Mineralogy, Niigata University, Ikarashi, Niigata 950-21, Japan
J. Akai
Affiliation:
Department of Geology and Mineralogy, Niigata University, Ikarashi, Niigata 950-21, Japan
W. S. Fyfe
Affiliation:
Department of Geology, University of Western Ontario, London, Ontario, N6A 5B7, Canada
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Abstract

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Cementing materials in the Arahama sand dune, Japan, were studied mineralogically and biogeochemically to gain a better understanding of the cause of hardening. The cementing material is a clay-organic complex composed of noncrystalline gels and a matrix of small, poorly crystalline particles showing 14–16-Å spacings. The gel materials appear to have transformed into the poorly crystalline particles, which have a high carbon content and Al/Si ratios of 2.2 to 2.0. These particles are slightly richer in Si and poorer in Fe than the gel materials themselves. The organic portion of the complex can be removed by H2O2 treatment, leaving a noncrystalline network-structure containing a dispersed granular component. Scanning auger-depth profiles of individual particles show a high surface concentration of C and O and an increase in the Al/Si ratio with depth. The energy-intensity distribution suggests a mixture of carbon compounds having a major core-line binding energy of a hydrocarbon. The gel-cementing materials in the sand dune may have been formed from biochemical weathering products of organic matter, which subsequently controlled the formation of clay-organic complexes.

Keywords

Cementing agentClay-organic complexGelSand duneScanning auger multiprobe analysisTransmission electron microscopyX-ray photoelectron spectroscopy
Type
Research Article
Information
Clays and Clay Minerals , Volume 37 , Issue 3 , June 1989 , pp. 219 - 226
Copyright
Copyright © 1989, The Clay Minerals Society

References

Berthelin, J. and Munier-Lamy, C., 1983 Microbial mobilization and preconcentration of uranium from various rock materials by fungi Ecol. Bull 35 395 – 401.Google Scholar
Bond, R. D. and Harris, J. R., 1964 The influence of the microflora on the physical properties of soils. I. Effects associated with filamentous algae and fungi Aust. J. Soil Res 2 111 – 122.CrossRefGoogle Scholar
Clark, D. T., Cromarty, B. J. and Dilks, A., 1978 A theoretical investigation of molecular core binding and relaxation energies in a series of oxygen-containing organic molecules of interest in the study of surface oxidation of polymers J. Polymer Science, Polymer Chem. Ed 16 3173 – 3184.CrossRefGoogle Scholar
Farmer, V. C., 1981 Possible roles of a mobile hydroxy-aluminum orthosilicate complex (proto-imogolite) and other hydroxyaluminum and hydroxy-iron species in podzolization Migrations Organo-Minerales dans les Sols Tempères Nancy, France Centre National de la Recherche Scientifique 275 – 279.Google Scholar
Huang, P. M., Violante, A., Huang, P. M. and Schnitzer, M., 1986 Influence of organic acids on crystallization and surface properties of precipitation products of aluminum Interaction of Soil Minerals with Natural Organics and Microbes Madison, Wisconsin Soil Science Society of America 159 – 221.CrossRefGoogle Scholar
Inoue, K. and Huang, P. M., 1986 Influence of selected organic ligands on the formation of allophane and imogolite Soil Sci. Soc. Amer. J 50 1623 – 1633.CrossRefGoogle Scholar
Nagarajah, S., Posner, A. M. and Quirk, J. P., 1970 Competitive adsorption of phosphate with polygalacturonate and other organic anions on kaolinite and oxide surfaces Nature (London) 228 83 – 84.CrossRefGoogle ScholarPubMed
Niigata Ancient Dune Research Group, 1967 Ancient dunes along the coast of the Japan Sea Quaternary Res 6 19 – 28.CrossRefGoogle Scholar
Research Group of Harden Soil, 1984 Characterization of the harden sand layer in Omiya, Japan Earth Science (Chikyu kagaku) 38 17 – 30.Google Scholar
Ross, G. J. and Kodama, H., 1979 Evidence for imogolite in Canadian soils Clays & Clay Minerals 27 297 – 300.CrossRefGoogle Scholar
Spyridakis, D. E., Chester, G. and Wilde, S. A., 1967 Kaolinization of biotite as a result of coniferous and deciduous seedling growth Soil Sci. Soc. Amer. Proc 31 203 – 210.CrossRefGoogle Scholar
Tazaki, K., 1979 Scanning electron microscopic study of imogolite formation from plagioclase Clays & Clay Minerals 27 209 – 212.CrossRefGoogle Scholar
Tazaki, K., Sudo, T., Shimoda, S., Yotsumoto, H. and Aida, S., 1980 Imogolite formed on weathered plagioclase Electron Micrographs of Clay Minerals Tokyo Kodansya 197 – 199.Google Scholar
Tazaki, K., Lindenmayer, Z. G. and Fyfe, W. S., 1988 Formation of ultra-thin Cu-S films on minerals: A weathering product from silicate-facies iron formation, Salobo, Carajas, Brazil Chem. Geol 67 285 – 294.CrossRefGoogle Scholar
Wada, K., Dixon, J. B. and Weed, S. B., 1977 Allophane and imogolite Minerals in Soil Environments Madison, Wisconsin Soil Science Society of America 603 – 638.Google Scholar
Wada, K. and Theng, B. K. G., 1980 Mineralogical characteristics of Andisols Soils with Variable Charge Lower Hutt, New Zealand New Zealand Soc. Soil Sci- 87 – 90.Google Scholar
Wada, K., Wilson, M., Kakuto, Y. and Wada, S., 1988 Synthesis and characterization of a hollow spherical form of monolayer aluminosilicate Clays & Clay Minerals 36 11 – 18.CrossRefGoogle Scholar