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Characterization of Brazilian palygorskite (Guadalupe region) and adsorptive behaviour for solvatochromic dyes

Published online by Cambridge University Press:  28 April 2021

Cristiane Gimenes de Souza Open the ORCID record for Cristiane Gimenes de Souza [Opens in a new window] ,
Tammy Caroline Lima de Jesus ,
Rafael Cavalcante dos Santos ,
Lívia Melo Bomfim ,
Luiz Carlos Bertolino ,
Débora França de Andrade ,
Luiz Antonio d´Avila  and
Luciana S. Spinelli
Cristiane Gimenes de Souza*
Affiliation:
Program in Nanotechnology Engineering, COPPE, Federal University of Rio de Janeiro, Cidade Universitária, Rio de Janeiro, CEP21941-909, Brazil
Tammy Caroline Lima de Jesus
Affiliation:
Program in Nanotechnology Engineering, COPPE, Federal University of Rio de Janeiro, Cidade Universitária, Rio de Janeiro, CEP21941-909, Brazil
Rafael Cavalcante dos Santos
Affiliation:
Program in Chemical and Biochemical Process Engineering, School of Chemistry, Federal University of Rio de Janeiro, Cidade Universitária, Rio de Janeiro, CEP21941-909, Brazil
Lívia Melo Bomfim
Affiliation:
School of Chemistry, Federal University of Rio de Janeiro, Cidade Universitária, Rio de Janeiro, CEP21941-909, Brazil
Luiz Carlos Bertolino
Affiliation:
Mineral Technology Center (CETEM), Cidade Universitária, Rio de Janeiro, CEP21941-908, Brazil
Débora França de Andrade
Affiliation:
Institute of Chemistry, Federal University of Rio de Janeiro, Cidade Universitária, Rio de Janeiro, CEP21941-908, Brazil
Luiz Antonio d´Avila
Affiliation:
Program in Chemical and Biochemical Process Engineering, School of Chemistry, Federal University of Rio de Janeiro, Cidade Universitária, Rio de Janeiro, CEP21941-909, Brazil
Luciana S. Spinelli
Affiliation:
Program in Nanotechnology Engineering, COPPE, Federal University of Rio de Janeiro, Cidade Universitária, Rio de Janeiro, CEP21941-909, Brazil Institute of Macromolecules, Federal University of Rio de Janeiro, Cidade Universitária, Rio de Janeiro, CEP21941-908, Brazil
*
*Email: [email protected]
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Abstract

This work presents the results of the physical characterization of palygorskite and its adsorptive behaviour for three solvatochromic dyes (Nile blue chloride (NBC), methylene blue (MTB) and dithizone (DTZ)). Adsorption isotherms were used to determine the maximum adsorption of the solvatochromic dyes on the palygorskite. The characterization of palygorskite was carried out via mineralogical and chemical analysis with X-ray diffraction, X-ray fluorescence, scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier-transform infrared spectroscopy, surface-charge measurement (ζ-potential), thermogravimetric analysis, textural analysis and cation-exchange capacity analysis. The material consists of palygorskite and quartz and its chemistry is dominated by SiO2, MgO and Fe2O3. The specific surface area and cation-exchange capacity of the palygorskite are 142 m2 g–1 and 41 cmol(+) kg–1, respectively. The SEM and TEM analyses showed a fibrous structure with fibres 20–100 nm long. The thermogravimetric analysis showed three endothermic events at 57.3°C, 171.8°C and 439.6°C. The adsorption capacities of the palygorskite for NBC (basic pH), MTB (basic pH) and DTZ (neutral pH) were 0.082, 0.013 and 0.102 g g–1, respectively. The adsorptions of NBC and MTB were fitted with the Langmuir isotherm model and the adsorption of DTZ was fitted with the Sips model.

Keywords

adsorption on materialsnanotechnologypalygorskitesolvatochromic dyes
Type
Article
Information
Clay Minerals , Volume 56 , Issue 1 , March 2021 , pp. 55 - 64
Copyright
Copyright © The Author(s), 2021. Published by Cambridge University Press on behalf of The Mineralogical Society of Great Britain and Ireland

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Footnotes

Associate Editor: Huaming Yang

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